Lists for Organic Effects

Increasing decreasing order of groups

Fri Sep 22, 2023

Inductive Effect

— I Effect

-NF₃⁺ > -NR₃⁺ >
-NH₃⁺ > -NO₂ > - CN > -CHO > -COR > -COOH > -F > -Cl > -Br > -I > -OR > -OH > -yne > -NH₂ > -Ph > -ene > -H

Inductive Effect

+ I Effect

-CH₂- > -NH^— >O^— >COO^— > -CR₃ > -CHR₂ > -R > -CH₃ > -T > -D > -H

Acidic Character

ane < ene < NH₃ < yne < ROH < Water < CH₃OH < Phenol < NaHCO₃ < p-Nitrophenol < RCOOH < Benzoic acid < HCOOH < Squaric acid ≈ Picric acid

Basic Character

List one

Guanidine > Secondary aliphatic > Tertiary aliphatic > Primary aliphatic >

Basic Character

List two

Carbocation Stability

(Benzylic)

(allylic)

(Vinylic)

Nucleophilicity

S₂O₃^2—> CN^— > I^— > PhNH₂ > SCN^— > OH^— > N^3— > Br^— > PhO^— >
CH₃COO^— > Cl^— > F^— > H₂O

+M Groups

-NH^—> -O^— > -NH2 > -OH > -OR > -NHCOR > -OCOR > -Ph > F >
> -Cl > -Br > -I > -NO

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